甲烷添加对氢气燃爆特性的影响

EFFECT OF METHANE ADDITION ON HYDROGEN COMBUSITON AND EXPLOSION CHARACTERISTICS

  • 摘要: 氢气掺混少量烃类气体有助于降低氢气储运和应用中燃爆风险。本文采用定容燃烧弹研究了甲烷掺混对氢气可燃极限和燃爆特性的影响规律,并对宽广当量比下富氢/甲烷/空气预混气以及纯氢气在空气中的燃烧爆炸特性开展对比研究。结果表明,随着甲烷添加量增加,可燃范围呈指数式降低,仅添加10%甲烷就能够使浓燃极限下降22.9%。但添加10%甲烷后,层流燃烧速度降低,化学计量比下爆炸时间增长20倍,热损失增大,导致最大爆炸压力略有降低,最大压力升高率显著降低。结合火焰发展的纹影图片分析可知,添加甲烷能够减弱可燃气燃爆危险性,不仅受层流燃烧速度降低的影响,还与火焰面裂纹和细胞状结构的减弱有关。

     

    Abstract: Hydrogen application can be carried out with the heat value of combustion maintained and the risk of explosion reduced, which is a feasible technical solution. In this paper, the effects of methane addition on the flammability limit and explosion characteristics of hydrogen are studied by using a constant volume combustion bomb. A comparative study of the explosion characteristics of hydrogen-enriched/methane/air and hydrogen/air is conducted under a wide equivalence ratio. Results show that the flammability range decreases exponentially with the increase of methane addition. The upper flammability limit can be reduced by 22.9% only by adding 10% methane. However, with 10% methane addition, its laminar burning velocity decreases, its explosion time under stoichiometric ratio increases by 20 times, and the heat loss also rises, which resulted in a slight drop of its maximum explosion pressure and a significantly lower value of maximum pressure rise rate. Combined with the analysis of the flame schlieren images, it can be seen that the addition of methane could reduce the risk of combustible gas explosion, which is not only affected by the reduction of laminar burning velocity, but also related to the weakening of flame surface cracks and cellular structure.

     

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